If you are still looking for the answer I have found it just a moment ago for my project.
Open DCOM Config Settings:
Start -> dcomcnfg.exe
Computer
Local Computer
Config DCOM
Search for Microsoft Word 97-2003 Documents -> Properties
Tab Identity, change from Launching User to Interactive User
Interop.Word Documents.Open is null
https://support.microsoft.com/en-us/kb/176799
http://forums.asp.net/t/1232621.aspx?Interop+Word+Document+Add+returning+null
http://forums.asp.net/t/1902899.aspx?Cannot+open+a+Word+doc
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